Embed Size (px)
Citation preview
4
5
61
23
BrO
O1'
Br2'
Br
3' 4
5
61
23
BrO
O1'
Br2'
Br
3'
3a 3b
4
5
61
23
BrO
O1'
Br2'
Br
3' 4
5
61
23
BrO
O1'
Br2'
Br
3'
3a 3b
2.02.53.03.54.04.55.05.56.06.57.0f1 (ppm)
-10
0
10
20
30
40
50
60
70
80
90
100
110
120CAM-OBr02-H500
2.75
2.97
2.69
1.00
0.98
0.91
0.88
1.89
71.
901
1.91
01.
914
3.84
53.
871
6.03
76.05
06.
063
6.06
86.
0776.
081
6.09
46.
1086.
620
6.62
46.
651
6.65
5
6.96
06.97
3
20253035404550556065707580859095100105110115120125130135140145150f1 (ppm)
-0.5
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
6.0
6.5
7.0
7.5
8.0
CAM-OBr02-C500
18.4
3618
.45055
.869
55.8
9956
.022
56.0
53
76.7
4577.0
0077
.255
108.
925
113.
209
115.
197
126.
759
129.
47912
9.50
812
9.82
1
148.
426
148.
588
4000 3800 3600 3400 3200 3000 2800 2600 2400 2200 2000 1800 1600 1400 1200 1000 800 600Wavenumber (cm-1)
0
8
16
24
32
40
48
56
64
72
80
88
96
Arb
itrar
y
740
834
927
959
986
1029
1097
1195
1256
1312
1339
14371463
1499
1567
1599
1651
2839
2911
2958
3002
3037
3084
3399
4000 3500 3000 2500 2000 1500 1000Wavenumber (cm-1)
8
16
24
32
40
48
56
64
72
80
88
96
104
%Tr
ansm
ittan
ce632
649666
751817
860938
9681031
107611781202
12701299
13771438
145314601504
15091561
15861608
166717121737
28332852
29302955
2996
2.02.53.03.54.04.55.05.56.06.57.0f1 (ppm)
-10
0
10
20
30
40
50
60
70
80
90
100
110
120
130CAM-alfaasarona-1H500
2.82
3.20
2.91
2.84
1.08
1.05
1.00
0.97
1.87
11.
874
1.88
41.
888
3.80
23.
844
3.86
8
6.05
56.06
86.
082
6.08
76.10
06.
113
6.12
76.
487
6.63
16.
635
6.66
36.
666
6.94
0
20253035404550556065707580859095100105110115120125130135140145150f1 (ppm)
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
CAM-alfaasarona-13C500
18.6
42
55.9
4055.9
7256
.333
56.3
6756
.516
56.5
52
76.7
4577.0
0077
.255
97.8
3897.8
80
109.
741
109.
741
118.
900
118.
900
124.
129
124.
129
124.
949
124.
949
143.
247
143.
247
150.
535
150.
535
4000 3500 3000 2500 2000 1500 1000Wavenumber (cm-1)
8
16
24
32
40
48
56
64
72
80
88
96
104
%Tr
ansm
ittan
ce632
649666
751817
860938
9681031
107611781202
12701299
13771438
145314601504
15091561
15861608
166717121737
28332852
29302955
2996
